The answer could be yes or no or maybe. Let’s start with the no. Many men tend to masturbate quickly, a habit they pick up as teens when they don’t want to get caught. It is believed that this habit causes them to lose the ability to control when they can have an orgasm which leads to premature ejaculation during intercourse. On the other hand, if a man is fairly sated sexually because he has masturbated recently, it might take him longer to become sufficiently aroused to have an orgasm during intercourse. But there could also be other factors causing a delayed orgasm. If he was afraid of causing a pregnancy, that could cause him problems. Of if he was having a lot of stress in his life that was distracting him and reducing his level of arousal, that could delay his orgasms. So you see, your question is impossible to answer without actually speaking to the man in question and finding out a bit more of what is going on.